The identity of those sides' eight opponents will be settled via a play-off round, one contested between the 16 teams who end up in positions nine through 24 in the league phase. Those clubs will be paired off across two legs, with the eight winners advancing to face the sides waiting for them.
| Favourite | Implied | Odds |
|---|---|---|
| Paris Saint Germain | 91% | 1.05 |
| Barcelona | 85% | 1.12 |
| Bayern Munich | 84% | 1.14 |
| Man United | 83% | 1.15 |
| VfB Stuttgart | 77% | 1.25 |
| PSV Eindhoven | 67% | 1.43 |